Anne Hathaway's on-screen debut was also the role that made her a household name! Hathaway instantly endeared herself to audiences worldwide as "Princess Mia Thermopolis" in 2001's The Princess Diaries, which marked the beginning of what would be a successful career for the actress.

Hugh Jackman had a very different career before he clawed his way into Hollywood as X-Men superhero "Wolverine"! In the years before his big screen debut, Jackman was a physical education teacher. However, playing the mutant in the 2000 movie made him an instant star!