It's impossible to think of the early 2000s and not reminisce about the "it" couple! Brad Pitt and Jennifer Aniston wed in 2000 and were dubbed the best Hollywood couple until that perfect image came to a crashing halt in 2005 when Pitt was caught red-handed in a steamy affair with his Mr. & Mrs. Smith costar, Angelina Jolie.
The affair hit tabloids globally, and it was a hot topic for a long while. Of course, now the two have reached a more amicable state, but we're not sure we can say the same for Jolie and Pitt, who are still in the middle of a tumultuous divorce.
